M A T E R I A L S A F E T Y D A T A S H E E T SECTION 1. - - - - - - - - - CHEMICAL IDENTIFICATION- - - - - - - - - - CATALOG #: 60-1001-50 NAME: TBTU SECTION 2. - - - - - COMPOSITION/INFORMATION ON INGREDIENTS - - - - - - CAS #:125700-67-6 MF: C11H16BF4N5O EC NO: 231- 15-9 SYNONYMS ALLBRI NATURAL COPPER * ANAC 110 * ARWOOD COPPER * BRONZE POWDER * CDA 101 * CDA 102 * CDA 110 * CDA 122 * C.I. 77400 * C.I. PIGMENT METAL 2 * COPPER (ACGIH:OSHA) * COPPER-AIRBORNE * COPPER BRONZE * COPPER-MILLED * COPPER SLAG-AIRBORNE * COPPER SLAG-MILLED * 1721 GOLD GOLD BRONZE * KAFAR COPPER * M 1 * M 3 * M 4 * M1 (COPPER) * M2 (COPPER) * M3 (COPPER) * M4 (COPPER) * M3R * M3S * OFHC CU * RANEY COPPER * SECTION 3. - - - - - - - - - - HAZARDS IDENTIFICATION - - - - - - - - - LABEL PRECAUTIONARY STATEMENTS FLAMMABLE (USA) HIGHLY FLAMMABLE (EU) IRRITANT IRRITATING TO EYES, RESPIRATORY SYSTEM AND SKIN. KEEP AWAY FROM SOURCES OF IGNITION - NO SMOKING. TAKE PRECAUTIONARY MEASURES AGAINST STATIC DISCHARGES. IN CASE OF CONTACT WITH EYES, RINSE IMMEDIATELY WITH PLENTY OF WATER AND SEEK MEDICAL ADVICE. WEAR SUITABLE PROTECTIVE CLOTHING, GLOVES AND EYE/FACE PROTECTION. SECTION 4. - - - - - - - - - - FIRST-AID MEASURES- - - - - - - - - - - IF SWALLOWED, WASH OUT MOUTH WITH WATER PROVIDED PERSON IS CONSCIOUS. CALL A PHYSICIAN. IF INHALED, REMOVE TO FRESH AIR. IF NOT BREATHING GIVE ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN. IN CASE OF CONTACT, IMMEDIATELY WASH SKIN WITH SOAP AND COPIOUS AMOUNTS OF WATER. IN CASE OF CONTACT, IMMEDIATELY FLUSH EYES WITH COPIOUS AMOUNTS OF WATER FOR AT LEAST 15 MINUTES. CONTAMINATION OF THE EYES SHOULD BE TREATED BY IMMEDIATE AND PROLONGED IRRIGATION WITH COPIOUS AMOUNTS OF WATER. SECTION 5. - - - - - - - - - FIRE FIGHTING MEASURES - - - - - - - - - - EXTINGUISHING MEDIA DRY CHEMICAL POWDER. DO NOT USE WATER. SPECIAL FIREFIGHTING PROCEDURES WEAR SELF-CONTAINED BREATHING APPARATUS AND PROTECTIVE CLOTHING TO PREVENT CONTACT WITH SKIN AND EYES. UNUSUAL FIRE AND EXPLOSIONS HAZARDS THIS MATERIAL, LIKE MOST MATERIALS IN POWDER FORM, IS CAPABLE OF CREATING A DUST EXPLOSION. FLAMMABLE SOLID. EMITS TOXIC FUMES UNDER FIRE CONDITIONS. SECTION 6. - - - - - - - - ACCIDENTAL RELEASE MEASURES- - - - - - - - - WEAR RESPIRATOR, CHEMICAL SAFETY GOGGLES, RUBBER BOOTS AND HEAVY RUBBER GLOVES. SWEEP UP, PLACE IN A BAG AND HOLD FOR WASTE DISPOSAL. AVOID RAISING DUST. VENTILATE AREA AND WASH SPILL SITE AFTER MATERIAL PICKUP IS COMPLETE. EVACUATE AREA. USE NONSPARKING TOOLS. SECTION 7. - - - - - - - - - - HANDLING AND STORAGE- - - - - - - - - - - REFER TO SECTION 8. SECTION 8. - - - - - - EXPOSURE CONTROLS/PERSONAL PROTECTION- - - - - - SAFETY SHOWER AND EYE BATH. MECHANICAL EXHAUST REQUIRED. WASH THOROUGHLY AFTER HANDLING. DO NOT BREATHE DUST. AVOID CONTACT WITH EYES, SKIN AND CLOTHING. AVOID PROLONGED OR REPEATED EXPOSURE. NIOSH/MSHA-APPROVED RESPIRATOR. COMPATIBLE CHEMICAL-RESISTANT GLOVES. CHEMICAL SAFETY GOGGLES. KEEP TIGHTLY CLOSED. STORE IN A COOL DRY PLACE. IRRITANT. SECTION 9. - - - - - - - PHYSICAL AND CHEMICAL PROPERTIES - - - - - - - PHYSICAL PROPERTIES SPECIFIC GRAVITY: 8.92 SECTION 10. - - - - - - - - -STABILITY AND REACTIVITY - - - - - - - - - STABILITY STABLE. CONDITIONS TO AVOID MAY DISCOLOR ON EXPOSURE TO AIR AND MOISTURE. INCOMPATIBILITIES STRONG ACIDS VIOLENT REACTION MAY OCCUR WITH ACETYLENE, AMMONIUM NITRATE, BROMATES, CHLORATES, IODATES, CHLORINE, CHLORINE TRIFLUORIDE, ETHYLENE OXIDE, FLUORINE, HYDROGEN PEROXIDE, HYDRAZINE MONONITRITE, HYDROGEN SULFIDE, HYDRAZOIC ACID, LEAD AZIDE, POTASSIUM PEROXIDE, SODIUM AZIDE, AND SODIUM PEROXIDE. REACTION OF COPPER WOOL, TRICHLOROACETIC ACID IN DIMETHYL SULFOXIDE IS VERY EXOTHERMIC. STRONG OXIDIZING AGENTS ACID CHLORIDES HALOGENS HAZARDOUS COMBUSTION OR DECOMPOSITION PRODUCTS NATURE OF DECOMPOSITION PRODUCTS NOT KNOWN. HAZARDOUS POLYMERIZATION WILL NOT OCCUR. SECTION 11. - - - - - - - - - TOXICOLOGICAL INFORMATION - - - - - - - - ACUTE EFFECTS CAUSES SKIN IRRITATION. CAUSES EYE IRRITATION. MATERIAL IS IRRITATING TO MUCOUS MEMBRANES AND UPPER RESPIRATORY TRACT. MAY BE HARMFUL BY INHALATION, INGESTION, OR SKIN ABSORPTION. CHRONIC COPPER POISONING IS TYPIFIED BY HEPATIC CIRRHOSIS, BRAIN DAMAGE AND DEMYELINATION, KIDNEY DEFECTS, AND COPPER DEPOSITION IN THE CORNEA AS EXEMPLIFIED BY HUMANS WITH WILSON'S DISEASE. IT HAS ALSO BEEN REPORTED THAT COPPER POISONING HAS LEAD TO HEMOLYTIC ANEMIA AND ACCELERATES ARTERIOSCLEROSIS. EXPOSURE CAN CAUSE: DAMAGE TO THE LUNGS STOMACH PAINS, VOMITING, DIARRHEA. BLOOD EFFECTS CHRONIC EFFECTS TARGET ORGAN(S): DAMAGE TO THE LUNGS RTECS #: GL5325000 COPPER TOXICITY DATA IPR-MUS LD50:3500 UG/KG 38MKAJ 2A,1623,1981 TARGET ORGAN DATA LUNGS, THORAX OR RESPIRATION (FIBROSIS, FOCAL) LUNGS, THORAX OR RESPIRATION (TUMORS) GASTROINTESTINAL (NAUSEA OR VOMITING) MATERNAL EFFECTS (UTERUS, CERVIX, VAGINA) EFFECTS ON FERTILITY (FEMALE FERTILITY INDEX) EFFECTS ON FERTILITY (PRE-IMPLANTATION MORTALITY) EFFECTS ON FERTILITY (POST-IMPLANTATION MORTALITY) EFFECTS ON EMBRYO OR FETUS (FETOTOXICITY) SPECIFIC DEVELOPMENTAL ABNORMALITIES (CENTRAL NERVOUS SYSTEM) SPECIFIC DEVELOPMENTAL ABNORMALITIES (MUSCULOSKELETAL SYSTEM) TUMORIGENIC (EQUIVOCAL TUMORIGENIC AGENT BY RTECS CRITERIA) ONLY SELECTED REGISTRY OF TOXIC EFFECTS OF CHEMICAL SUBSTANCES (RTECS) DATA IS PRESENTED HERE. SEE ACTUAL ENTRY IN RTECS FOR COMPLETE INFORMATION. SECTION 12. - - - - - - - - - ECOLOGICAL INFORMATION - - - - - - - - - - DATA NOT YET AVAILABLE. SECTION 13. - - - - - - - - - DISPOSAL CONSIDERATIONS - - - - - - - - - MATERIAL IN THE ELEMENTAL STATE SHOULD BE RECOVERED FOR REUSE OR RECYCLING. OBSERVE ALL FEDERAL, STATE AND LOCAL ENVIRONMENTAL REGULATIONS. SECTION 14. - - - - - - - - - - TRANSPORT INFORMATION - - - - - - - - - CONTACT SEVERN BIOTECH FOR TRANSPORTATION INFORMATION. SECTION 15. - - - - - - - - - REGULATORY INFORMATION - - - - - - - - - - EUROPEAN INFORMATION HIGHLY FLAMMABLE IRRITANT R 1 HIGHLY FLAMMABLE R 36/37/38 IRRITATING TO EYES, RESPIRATORY SYSTEM AND SKIN. S 16 KEEP AWAY FROM SOURCES OF IGNITION - NO SMOKING. S 33 TAKE PRECAUTIONARY MEASURES AGAINST STATIC DISCHARGES. S 26 IN CASE OF CONTACT WITH EYES, RINSE IMMEDIATELY WITH PLENTY OF WATER AND SEEK MEDICAL ADVICE. S 36/37/39 WEAR SUITABLE PROTECTIVE CLOTHING, GLOVES AND EYE/FACE PROTECTION. REVIEWS, STANDARDS, AND REGULATIONS OEL=MAK ACGIH TLV-TWA 1 MG(CU)/M3, DUST, MIST DTLVS* TLV/BEI,1999 ACGIH TLV-TWA 0.2 MG(CU)/M3, FUME DTLVS* TLV/BEI,1999 EPA FIFRA 1988 PESTICIDE SUBJECT TO REGISTRATION OR RE-REGISTRATION FEREAC 54,7740,1989 MSHA STANDARD-AIR:TWA 0.1 MG/M3 (FUME,DUSTS & MISTS) DTLVS* 3,59,1971 OSHA PEL (GEN INDU):8H TWA 0.1 MG(CU)/M3, FUME CFRGBR 29,1910.1000,1994 OSHA PEL (GEN INDU):8H TWA 1 MG(CU)/M3, DUSTS AND MISTS CFRGBR 29,1910.1000,1994 OSHA PEL (CONSTRUC):8H TWA 0.1 MG(CU)/M3, FUME CFRGBR 29,1926.55,1994 OSHA PEL (CONSTRUC):8H TWA 1 MG(CU)/M3, DUSTS AND MISTS CFRGBR 29,1926.55,1994 OSHA PEL (SHIPYARD):8H TWA 0.1 MG(CU)/M3, FUME CFRGBR 29,1915.1000,1993 OSHA PEL (SHIPYARD):8H TWA 1 MG(CU)/M3, DUSTS AND MISTS CFRGBR 29,1915.1000,1993 OSHA PEL (FED CONT):8H TWA 0.1 MG/M3, FUME CFRGBR 41,50-204.50,1994 OSHA PEL (FED CONT):8H TWA 1 MG/M3, DUSTS AND MISTS CFRGBR 41,50-204.50,1994 OEL-ARAB REPUBLIC OF EGYPT:TWA 0.1 MG/M3 (FUME) JAN 1993 OEL-AUSTRIA: MAK 0.1 MG/M3 (FUME), JAN1999 OEL-AUSTRIA: MAK 1 MG/M3, JAN1999 OEL-AUSTRALIA:TWA 0.2 MG/M3 (FUME) JAN 1993 OEL-AUSTRALIA:TWA 1 MG/M3 (DUST) JAN 1993 OEL-DENMARK: TWA 0.1 MG/M3, JAN1999 OEL-BELGIUM:TWA 0.2 MG/M3 (FUME) JAN 1993 OEL-BELGIUM:TWA 1 MG/M3 (DUST) JAN 1993 OEL-FRANCE: VME (DUST) 1 MG/M3, JAN1999 OEL-FINLAND:TWA 0.2 MG/M3 (FUME) JAN 1993 OEL-POLAND: MAC(TWA) DUST 1 MG/M3, MAC(STEL) DUST 2 MG/M3, JAN1999 OEL-POLAND: MAC(TWA) FUME 0.1 MG/M3, MAC(STEL) FUME 0.3 MG/M3, JAN1999 OEL-FINLAND:TWA 1 MG/M3 (DUST) JAN 1993 OEL-GERMANY:TWA 0.1 MG/M3 (FUME) JAN 1993 OEL-GERMANY:TWA 1 MG/M3 (DUST) JAN 1993 OEL-HUNGARY:TWA 0.2 MG/M3;STEL 0.4 MG/M3 (DUST) JAN 1993 OEL-INDIA:TWA 0.2 MG/M3 (FUME) JAN 1993 OEL-THE NETHERLANDS:TWA 02 MG/M3 (FUME) JAN 1993 OEL-THE NETHERLANDS:TWA 1 MG/M3 (DUST) JAN 1993 OEL-THE PHILIPPINES:TWA 1.0 MG/M3 (FUME) JAN 1993 OEL-RUSSIA:STEL 0.5 PPM (1 MG/M3) (DUST) JAN 1993 OEL-SWEDEN:TWA 0.2 MG/M3 (RESP. DUST) JAN 1993 OEL-SWEDEN:TWA 0.2 MG/M3 (FUME) JAN 1993 OEL-SWEDEN:TWA 1 MG/M3 (TOTAL DUST) JAN 1993 OEL-SWITZERLAND:TWA 0.1 MG/M3;STEL 0.2 MG/M3 (FUME) JAN 1993 OEL-SWITZERLAND:TWA 1 MG/M3;STEL 1 MG/M3 JAN 1993 OEL-THAILAND:TWA 0.1 MG/M3 (FUME) JAN 1993 OEL-THAILAND:TWA 1 MG/M3 JAN 1993 OEL-UNITED KINGDOM:TWA 0.2 MG/M3 (FUME) JAN 1993 OEL-UNITED KINGDOM:TWA 1 MG/M3 JAN 1993 OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA CHECK ACGIH TLV OEL IN NEW ZEALAND, SINGAPORE, VIETNAM CHECK ACGIH TLV NIOSH REL TO COPPER, DUSTS AND MISTS-AIR:10H TWA 1 MG/M3 NIOSH* DHHS #92-100,1992 NIOSH REL TO COPPER, FUME-AIR:10H TWA 0.1 MG/M3 NIOSH* DHHS #92-100,1992 NOHS 1974: HZD M2276; NIS 27; TNF 1213; NOS 35; TNE 24737 NOHS 1974: HZD 20115; NIS 176; TNF 12177; NOS 105; TNE 224406 NOES 1983: HZD X5915; NIS 5; TNF 162; NOS 5; TNE 11889; TFE 421 NOES 1983: HZD X5983; NIS 51; TNF 4558; NOS 45; TNE 53282; TFE 8758 NOES 1983: HZD X6807; NIS 2; TNF 16; NOS 2; TNE 625 NOES 1983: HZD X8588; NIS 3; TNF 204; NOS 7; TNE 9443 NOES 1983: HZD 20115; NIS 296; TNF 59839; NOS 158; TNE 920449; TFE 72821 EPA TSCA SECTION 8(B) CHEMICAL INVENTORY EPA TSCA SECTION 8(D) UNPUBLISHED HEALTH/SAFETY STUDIES ON EPA IRIS DATABASE EPA TSCA TEST SUBMISSION (TSCATS) DATA BASE, DECEMBER 1999 NIOSH ANALYTICAL METHOD, 1994: ELEMENTS BY ICP, 7300 NIOSH ANALYTICAL METHOD, 1994: COPPER (DUST AND FUME), 7029 NIOSH ANALYTICAL METHOD, 1994: ELEMENTS IN BLOOD OR TISSUE, 8005 NIOSH ANALYTICAL METHOD, 1994: METALS IN URINE, 8310 OSHA ANALYTICAL METHOD #ID-125G U.S. INFORMATION THIS PRODUCT IS SUBJECT TO SARA SECTION 313 REPORTING REQUIREMENTS. SECTION 16. - - - - - - - - - - OTHER INFORMATION- - - - - - - - - - - - THE ABOVE INFORMATION IS BELIEVED TO BE CORRECT BUT DOES NOT PURPORT TO BE ALL INCLUSIVE AND SHALL BE USED ONLY AS A GUIDE. SEVERN BIOTECH SHALL NOT BE HELD LIABLE FOR ANY DAMAGE RESULTING FROM HANDLING OR FROM CONTACT WITH THE ABOVE PRODUCT.